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This skin looks awesome. The sidebar is logically designed. And I like the way you have grouped the voting up/ down and created a toolbar which can be added on to with other features.
I would like to see some differentiation between the question and answers. May be the answers section can have smaller avatars and shifted to the right by a tab space? Or the question could be made more prominent by increasing the shadow effect.
Also as @Evgeny thinks, I feel the very prominent comment button may be a distraction when the idea is to get people to post answers as answers not a comment on the question.